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It is claimed that all of the pressure scales of the reported melting curvesderived by diamond anvil cell experiments require a correction which takes intoaccount the pressure thermal shift, where vanadium is an illustrative example.The linear behavior of the thermal pressure (Pth) vs. the temperature, aspredicted by first principles theoretical assumptions is then experimentallyconfirmed. This allows extrapolation to determine of the actual pressure andthermal temperature at the melt. Accounting for the role of the pressuretransmitting media in diamond anvil cell experiments, the analysis of elementalvanadium melting curve is presented. It is shown that the appropriatecorrection of shock waves melting data which takes into account the radiationabsorbed by the LiF window, applies only to vanadium metal. The correctpressure scale of vanadium metal as derived by diamond anvil cell is presented.

The actual pressure and temperature at the melt of elemental vanadium