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Traditional MXenes with intriguing mechanical and electronic properties,together with the fertilities of elemental compositions and chemicaldecorations have aroused much attentions. However, the semiconducting traitswith direc band gap are extremetely rare among reported MXenes. Thus,broadening the family of MXene beyond carbides and nitrides with uniquebehaviors is still an extraordinary and fascinating field.

Halogenation induced transition of superconductor-to-semiconductor in MXene-like MOene with direct band gap and long carrier lifetime