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A statistical numerical analysis of thermogravimetric measurements(temperature, mass variation, oxygen pressure) leads to a new equilibrium phasediagram T-P-X of the iron monoxide or w\"ustite FeOx. Three varieties or pseudophases W1, W2, W3 are revealed above 911 {\textdegree}C, three others W'1, W'2,W'3 below. This diagram displays their subfields, and shows 25 invariant pointsbetween stable phases and 8 possible invariant points between metastablephases. A thermodynamic approach is pointed out, which makes possible tocharacterize the point defects and their clusters as components of the crystallattice.

Thermogravimetric study of the non-stoichiometric w\"ustite FeOx. Pseudo phases w i and w' i . New T-P-X equilibrium phase diagram