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Micro emulsions (MEs) offer an exceptionally broad spectrum of applicationscovering sensing, electrosynthesis, supercapacitors and redox-flow batteries.Herein, we develop the theory for a sophisticated electrochemicalcharacterizion of MEs with a spatially and time-invariant anisotropy in thediffusion domain by means of cyclic voltammerty (CV). By introducing spatiallydependent diffusion coefficients into Ficks' first law, we derive a modifieddiffusion equation to simulate any inherent anisotropy of the ME underinvestigation. Moreover, by formulating an extended second-order homogeneoussix-member square scheme for a kinetically controlled two-step two-electronreaction we capture the intricate entanglement of chemical and electrochemicalequilibria. Our theoretical concept is finally validated by experimental CVdata for the ME based two-step redox reaction of methyl-viologen which pavesthe way for a quantitative electrochemical characterization MEs.

A Theoretical Framework for the Electrochemical Characterization of Anisotropic Micro-Emulsions