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Superconducting crystals with lack of inversion symmetry can potentially hostunconventional pairing. However, till date, no direct conclusive experimentalevidence of such unconventional order parameters in non-centrosymmetricsuperconductors has been reported. In this paper, through direct measurement ofthe superconducting energy gap by scanning tunnelling spectroscopy, we reportthe existence of both $s$-wave (singlet) and $p$-wave (triplet) pairingsymmetries in non-centrosymmetric Ru$_7$B$_3$. Our temperature and magneticfield dependent studies also indicate that the relative amplitudes of thesinglet and triplet components of the order parameter change differently withtemperature.

Spectroscopic evidence of mixed angular momentum symmetry in non-centrosymmetric Ru$_7$B$_3$