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Solutions of wormlike micelles can form cross-linked networks on microscopiclength scales. The unique mechanical properties of these complex fluids aredriven by the interplay between the network structure and dynamics which areinvestigated by plate-plate rheometry and X-ray photon correlationspectroscopy~(XPCS) nanorheology. Intensity auto-correlation functions oftracer nanoparticles~(NPs) dispersed in micelle solutions were recorded whichcaptured both the slow structural network relaxation and the short-timedynamics of NPs trapped in the network. The results are indicative of aresonance-like dynamic behavior of the network on the nanoscale that developsas a consequence of the intrinsic short-range rigidity of individual micellechains.

Nanoscale Rigidity in Cross-Linked Micelle Networks Revealed by XPCS Nanorheology