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Recently, low-dimensional organic-inorganic hybrid halide compounds havearoused great attention in the optoelectronic field, due to the unique topologyand optical properties. Herein, we report an Mn4+ doped [N(CH3)4]2TiF6zero-dimensional organic-inorganic hybrid phosphor, which could not onlyexhibit very narrow and pure red emission, but also maintain efficient emissionintensity at room temperature. The crystal structure, photoluminescenceproperties and temperature sensing application are discussed. The excellenttemperature dependent luminescent properties are attributed to the rigidstructure and isolated MnF62- octahedra in the total crystal framework. Theseresults will help design suitable materials and devices in both warm whitelight emitting diodes and optical sensors.

Zero-Dimensional Organic-Inorganic Hybrid Material with Ultra-Narrow-Red Emission at Room Temperature