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Preparation technology, the structure determination, multiband luminescenceand nonlinear optical properties of the chalcogenide glasses are subject ofpresent work. The glass samples with two different Er content were prepared byclassical two-stage melt-quenching method. Glass state and morphology wereconfirmed by X-ray and EDS techniques. Influence of the Erbium doping on theluminescence and NLO properties was investigated.

Photoluminescence features and nonlinear-optical properties of the Ag0.05Ga0.05Ge0.95S2eEr2S3 glasses