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The deviation of positions of atoms from their ideal lattice sites incrystalline solid state systems causes distortion and can lead to variation instructural [1] and functional properties [2]. Distortion in molecular systemshas been traditionally understood in the term of Jahn-Teller distortion [3],while for the one-dimensional chain of metals, the Peierls distortion mechanismhas been proposed [4]. In a real three dimensional metallic systems, afundamental description of the distortion is missing, which we need to designalloys with attractive structural properties. The present investigationpresents the evolution of distortion in metallic systems in terms ofmagnetovolume effects arising due to magnetic ground-state of the system.Particularly the significant distortion in the case of Cr due to presence ofother transition metals is seen. Cr alloyed with transition metals as acandidate system to study the correlation between charge disproportion,spin-flip, magnetovolume effects and Fermi surface nesting. This study providesa novel explanation of strengthening effect of Cr observed in alloys due to itsunique magnetic properties.

Electron spin mediated distortion in metallic systems