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We describe a theory on photo-thermoelectric properties of a semiconductor,which include photo-conductivity, photo-Seebeck coefficient, and photo-Halleffect. We demonstrate that these properties provide a powerful tool for thestudy of carrier transport in semiconductors. Even though photo-carriergeneration is a complicated process which often prohibits quantitative analysisas their species or numbers are not known. Using bulk samples seems even lesslikely as the photo-carrier only affect a thin layer. Our method will allowresearchers to bypass these difficulties, to use only measured properties anddetermine both electron and hole mobilities as well as the ratio betweenelectrons and holes from a bulk sample. We provide initial experimentverification of our theory in the end using two distinctively differentsemiconductors.

Photo-thermoelectric properties and their use in study of transport properties of both carriers from a single bulk sample