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The scaling relationships between the adsorption energies of differentreaction intermediates have a tremendous effect in the field of surfacescience, particularly in predicting new catalytic materials. In the last fewdecades, these scaling laws have been extensively studied and interpreted by anumber of research groups which makes them almost universally accepted. In thiswork, we report the breakdown of the standard scaling law in bimetallictransition metal (TM) magnetic surfaces for O and OH adsorbates, whereadsorption energies are estimated using density functional theory (DFT).Wepropose that the scaling relationships do not necessarily rely solely on theadsorbates, they can also be strongly dependent on the surface properties.

Scaling relation for the adsorption energies at bimetallic magnetic surfaces: Role of surface magnetic moment and work-function