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The comparative study of structural, electronic properties, topology of theFermi surface, and the features of chemical bonding in layered1111-oxyarsenides LaRhAsO and LaIrAsO has been performed based on the resultsof ab initio modeling of their electronic structure. It was established thatonly weak sensitivity with respect both to electron and hole doping is expectedfor LaIrAsO being non-magnetic metal, however, the Rh-containing compoundshould be characterized with weak band magnetism, and the hole doping isexpected to be able to move its ground state away from the boundary of magneticinstability. The mentioned feature allows to consider LaRhAsO oxyarsenide as apossible "electron analogue" of LaFeAsO compound being the initial phase forthe layered FeAs-superconductors.

Structural, electronic properties and the features of chemical bonding in layered 1111-oxyarsenides LaRhAsO and LaIrAsO: ab initio modeling