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Phosphors serve as color conversion layers to generate white light withvarying optical features including CRI, CCT, and luminous efficacy. However,they have been produced in harsh synthesis conditions such as high temperature,high pressure, and/or employing a huge amount of solvents. In this work,facile, water-based and a rapid method has been proposed to fabricatelanthanide doped hydroxide-based phosphors. In this sense, submicrometer-sizedY(OH)3:Eu3+ particles, as red phosphor, were synthesized in water at ambientconditions in <60 min reaction time. The doping ratio is controlled from 2.5 to20% in terms of mole. Meanwhile, first principle calculations were alsoperformed on Y(OH)3:Eu3+ to understand the preferable doping scenario and itsoptoelectronic properties. As an application, these fabricated red phosphorswere integrated into PDMS/YAG:Ce3+ composite to generate white light. Theresulting white light showed a remarkable improvement (~24%) for LER, a slightreduction of CCT (from 3900K to 3600K), and an unchanged CRI (~60) as theamount of Y(OH)3:Eu3+ increases.

Green Fabrication of Lanthanide doped Hydroxide-based Phosphors: Y(OH)3:Eu3+ Nanoparticles for White Light Generation