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Thiolate-protected gold nanoclusters represent atomically well-defined activecenters for catalysis with resolved crystal structures, enabling the creationof a homogeneous and defined surface. The correlation of characterization viaFT-IR spectroscopy with kinetics studies gives insight into the gold clustersactivity and tests their utilization to bridge the gap between organometalliccomplex-based homogenous catalysis and nanoparticle based heterogeneouscatalysis as well as the gap between the bulk crystal structure model catalysisand real-world catalysis.

Carbon Monoxide Adsorption and Carbon Monoxide Oxidation Studies on Thiolate Supported Gold Nanoclusters Dispensed on Metallic Oxides