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We predict the structural, electronic and optic properties of the inorganicGe-based halide perovskites AGeX3 (A = Cs, Rb; X = I, Br, Cl) by usingfirst-principles method. In particular, absolute electronic energy band levelsare calculated using two different surface terminations of each compound,reproducing the experimental band alignment.

Structural and optoelectronic properties of the inorganic perovskites AGeX3 (A = Cs, Rb; X = I, Br, Cl) for solar cell application