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Computer simulation study of phase transitional behaviour of cholesterolmolecules embedded with terminal dipole is reported. In this work,coarse-grained modeling of cholesteric molecules is done to study the influenceof the coupled chiral and dipolar interactions on macroscopicliquid-crystalline phase formation. This NVT molecular dynamics simulationstudy demonstrates the formaton of novel Smectic Blue phase(BP\textsubscript{Sm}) which is a recent experimentally discovered chiralphase. Our study reveals that the higher strength of chiral interaction inducesblue phase, whereas, larger dipolar interaction can bring bilayered smecticblue phase.

Novel chiral smectic phase generation in systems of polar ellipsoidal molecules with reflection asymmetry: A molecular dynamics simulation study