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The solubility of a "heavy" alkane (solute) in a "light" alkane (solvent) isgenerally temperature dependent. Moreover, it is determined by the molar massesof the solute and solvent. In the current paper, published solubility data forbinary normal-alkane mixtures is reviewed (solid-liquid equilibrium). A totalof 43 unique solute-solvent data-sets, obtained from a total of 24 publishedexperimental studies, are collected and presented in a systematic manner. Basedon thermodynamic considerations and the experimental data, it is demonstratedthat there is a log-linear relationship between the solubility and thetemperature in the dilute range. Linear regression is employed to 1) obtaindata-set-specific solubility-temperature best-fit parameters and 2) obtain ageneral correlation between the solubility and the solvent and solute molarmasses and the temperature. Finally, it is demonstrated that the developedcorrelation carries predictive power even for multi-component mixtures byutilizing solvent and solute average molar masses.

A Review of Experimental Solubilities and a General Correlation between  the Temperature-Dependent Solubility and Solute and Solvent Molar Masses for  Binary n-Alkane Mixtures