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We developed a generalized replicated liquid theory for glassy phases ofnon-spherical uniaxial molecules and colloids, which becomes exact in the largedimensional limit $d\to\infty$. We then applied the scheme to patchy colloidswith sticky patches at their heads and tails. The system exhibits rich phasebehaviors involving the translational and orientational degrees of freedom. Wefound a novel glass-glass transition between glasses with large/smallorientational fluctuations.

Translational and orientational glass transitions in the  large-dimensional limit : a generalized replicated liquid theory and an  application to patchy colloids