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Ionic Liquids (ILs) are organic molten salts characterized by the totalabsence of solvent. They show remarkable properties: low vapor pressure, highionic conductivity, high chemical, thermal and electrochemical stability. Theseelectrolytes meet therefore key criteria for the development of safe energystorage systems. Due to a competition between electrostatic and van der Wallsinteractions, ILs show an uncommon property for neat bulk liquids: theyself-organize in transient nanometric domains. In ILs-based electrochemicaldevices, this fluctuating nano-segregation acts as energy barriers to the longrange diffusional processes and hence to the ionic conductivity. Here, we showhow the ionic conductivity of ILs can be increased by more than one order ofmagnitude by exploiting one dimensional (1D) confinement effects inmacroscopically oriented carbon nanotube (CNT) membranes. We identify 1D CNTmembranes as promising separators for high instant power batteries.

Ionic liquids confined in 1D CNT membranes:gigantic ionic conductivity