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Solving the atomic structure of metallic clusters is fundamental tounderstanding their optical, electronic, and chemical properties. We report thestructure of Au$_{\text{146}}$(p-MBA)$_{\text{57}}$ at subatomic resolution(0.85 {\AA}) using electron diffraction (MicroED) and atomic resolution byX-ray diffraction. The 146 gold atoms may be decomposed into two constituentsets consisting of 119 core and 27 peripheral atoms. The core atoms areorganized in a twinned FCC structure whereas the surface gold atoms follow aC$_{2}$ rotational symmetry about an axis bisecting the twinning plane. Theprotective layer of 57 p-MBAs fully encloses the cluster and comprisesbridging, monomeric, and dimeric staple motifs.Au$_{\text{146}}$(p-MBA)$_{\text{57}}$ is the largest cluster observedexhibiting a bulk-like FCC structure as well as the smallest gold particleexhibiting a stacking fault.

MicroED structure of Au146(p-MBA)57 at subatomic resolution reveals a twinned FCC cluster