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Two models have been proposed for the interconnection of the defect Gibbsenergy g^i with bulk properties almost 60 and 30 years ago, respectively. Theone, proposed by Zener, assumes that g^i can be accounted for the work thatgoes into straining the lattice and hence it is proportional to the shearmodulus of the solid. The other, considers that, since g^i corresponds to anisobaric and isothermal process, it should be proportional to the isothermalbulk modulus and the mean volume per atom. The results of these two models arecompared for different processes (defect formation, self-diffusion activation,hetero-diffusion) in a variety of solids including metals (fcc, bcc andtetragonal) as well as solids that exhibit superionic behavior. We find thatthe latter model does better than the former.

Interconnection of point defect parameters in solids with bulk properties: A review