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We introduce a self-consistent multi-species kinetic theory based on thestructure of the narrow voltage-gated potassium channel. Transition ratesdepend on a complete energy spectrum with contributions including thedehydration amongst species, interaction with the dipolar charge of the filterand, bulk solution properties. It displays high selectivity between speciescoexisting with fast conductivity, and Coulomb blockade phenomena, and it fitswell to data.

Kinetic model of selectivity and conductivity of the KcsA filter