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The fundamental principles underlying the arrangement of elements into solidcompounds with an enormous variety of crystal structures are still largelyunknown. This study presents a general overview of the structure typesappearing in an important subset of the solid compounds, i.e., binary andternary compounds of the 6A column oxides, sulfides and selenides. It containsan analysis of these compounds, including the prevalence of various structuretypes, their symmetry properties, compositions, stoichiometries and unit cellsizes. It is found that these compound families include preferredstoichiometries and structure types that may reflect both their specificchemistry and research bias in the available empirical data. Identification ofnon-overlapping gaps and missing stoichiometries in these structure populationsmay be used as guidance in the search for new materials.

The structure and composition statistics of 6A binary and ternary crystalline materials