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The mechanisms of phase change of argon during picosecond laser internalablation are studied using molecular dynamics simulations. It is found thatpropagation of stress wave and fluctuation of temperature are periodical. Thephase change process from solid to liquid to supercritical fluid then back tosolid occurs as combined results of heating and the propagation of tensilestress wave induced by the laser pulse and the limited internal space.

Solid-to-super Critical Phase Change during Laser Internal Ablation