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Quantum corrections to the classical pressure are obtained for Lennard-Jonesmodels of argon, neon, and helium using classical Metropolis algorithm computersimulations. The corrections for non-commutativity are obtained to fourth orderin Planck's constant. Compared to the classical virial pressure on allisotherms at liquid-like densities, the quantum correction is found to be${\cal O}(10^{-2})$ for argon, ${\cal O}(10^{0})$ for neon, and ${\calO}(10^{3})$ for helium. The first order correction due to wave functionsymmetrization is also obtained, but this is relatively negligible.

Quantum Statistical Mechanics Results for Argon, Neon, and Helium Using Classical Monte Carlo