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Two different probes, viz., 111In/111Cd and 181Hf/181Ta, simultaneously havebeen incorporated in both pure rutile and Hafnium (Hf) -doped rutile TitaniumDioxide (TiO2) systems following a soft chemical method. The local informationaround two different probe sites in the same sample could be extracted in asingle Time Differential Perturbed Angular Correlation (TDPAC) measurementusing LIST mode data acquisition. The two probes were incorporated in therutile samples by co-precipitation technique and then annealed at 1273K for 10hto get the rutile structure. The rutile structure was identified by thehyperfine parameters, viz., quadrupole frequency ({\omega}Q) and asymmetry(eta). At 111Cd site, {\omega}Q=16.8(1) Mrad/s and eta=0.19(1) while at 181Tasite, {\omega}Q=127.2(2) Mrad/s and eta=0.56(1). Due to the doping of Hf at 5and 10 atom%, the sample partially lost the purity of the crystal and the facthas been reflected at both the probe sites.

Study of Electric Quadrupole Perturbation at Multiple Probe Sites in  Hf-doped Rutile in a Single Perturbed {\gamma}-{\gamma} Angular Correlation  Measurement