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The valence band offsets (VBO) for the \b{eta}-type A3B6 layered compoundsdepending on the thickness of the crystals have been investigated from thefirst principles, based on the density functional theory. To simulate thestructure of a given thickness the periodic slab model was used. Two adjacentcrystal slabs consisting of several layers were separated by a vacuum region oftwo-layer width. It is shown that at the crystal thickness more than 12 layers,photothreshold practically becomes independent on the thickness of the crystal.

First principles calculation of the valence band offsets for \b{eta}- polytype of A3B6 layered crystals