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In a floating water bridge the total radiation scattering of water stressedby a moderately strong electric field (1mV/nm) was compared to water without anapplied electric field using X-ray and small angle neutron scattering.Structure refinement was carried out using the EPSR method and the TIP4P/2005water model. These results did not reveal a significant difference in the localstatic structure of water however analysis of the simulation indicated that themodeled local potential energy surface reveals a departure between electricallystressed and unstressed water. The observed differences show that the localenvironment is changed by the applied electric field although weak relative tothe intermolecular coulombic field. When discussing the results we show thatthe current methods used to simulate the pair potentials are still insufficientto treat such non-equilibrium systems and further simulation techniques have tobe developed to properly reconstruct the microscopic dielectric relaxationprocess.

The local structure of electrically stressed liquid water and implications for modelling of dielectric relaxation