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A highly sensitive optical capillary electrophoresis measurement method basedon a nanofluidic optical fiber platform is presented. By using scalingarguments and considering realistic instrument limitations, I underline thefeasibility of measuring the electrophoretic mobility of a singlefreely-diffusing nanoparticle or macromolecule in vitro, continuously andindefinitely, with microsecond time resolution. The high speed of thistechnique opens up new possibilities for studying reaction kinetics at thesingle molecule level.

How to replace the oil droplet in Millikan's experiment with a single virus