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Dipole moment functions of isotopomeric molecular ions, HCl+ and DCl+, areconsidered in the two coordinate systems, center of mass of nuclei and centerof nuclear charges, both through simple analytical derivations and ab initiocalculations of electronic structure at various interatomic separations. Anorigin of the different values for dipole moments of the isotopomers isdiscussed and demonstrated by the calculation data.

On calculations of dipole moments of HCl+ and DCl+ molecular ions