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Ten years ago, Liu and co-workers measured pair-correlated product speed andangular distributions for the OH+CH4/CD4 reactions at the collision energy of ~10 kcal/mol [B. Zhang, W. Shiu, J. J. Lin and K. Liu, J. Chem. Phys 122, 131102(2005); B. Zhang, W. Shiu and K. Liu, J. Phys. Chem. A 2005, 109, 8989].Recently, two of us could semi-quantitatively reproduce these measurements byperforming full-dimensional classical trajectory calculations in a quantumspirit on an ab-initio potential energy surface of their own [J.Espinosa-Garcia and J. C. Corchado, Theor Chem Acc, 2015, 134, 6 ; J. Phys.Chem. B, Article ASAP, DOI: 10.1021/acs.jpcb.5b04290]. The goal of the presentwork is to show that these calculations can be significantly improved by addinga few more constraints to better comply with the experimental conditions.Overall, the level of agreement between theory and experiment is remarkableconsidering the large dimensionality of the processes under scrutiny.

Pair-correlated product speed and angular distributions for the  OH+CH4/CD4 reactions: Further remarks on their classical trajectory  calculations in a quantum spirit