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The effects of off-stoichiometry and elemental substitution on electronicproperties of iron-based ladder compound BaFe$_{2}$S$_{3}$ are investigated.Resistivity and magnetization are revealed to be quite sensitive to thestoichiometry of Fe atoms, and 10 \% deficiency at Fe sites reduces theantiferromagnetic transition temperature by 40 K. The antiferromagnetictransition temperature decreases even faster and collapse to zero with holedoping through 10 \% K substitution at Ba site, while the antiferromagneticordering phase remains with electron doping through 20 \% Co substitution at Fesite. Such electron-hole asymmetry is opposite to two-dimensional iron-basedsuperconductors, and can be explained on the basis of both itinerant andlocalized electronic pictures.

The Effects of Stoichiometry and Substitution in quasi-one-dimensional iron-chalcogenide BaFe$_{2}$S$_{3}$