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Infrared spectra of various polymers were treated statistically. It wasestablished that for the absorbance spectra the Benford distribution of leadingdigits takes place, whereas the distribution of leading digits fortransmittance spectra is random. This observation may be explained by the factthat the value of transmittance Tr is restricted, due to the physical reasons,whereas the value of absorbance is not. Moreover, the transmittance andabsorbance A are interrelated by the logarithmic dependence . This observationsupplies the idea that the Benford's law is valid in the situations, whenlogarithmic dependencies take place.

Benford's Law, its applicability and breakdown in the IR Spectra of polymers