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It is shown for two electron atoms that ground-state wavefunctions of theform \begin{equation}  \Psi(\vec{r_{1}}, \vec{r_{2}})=\phi(\vec{r_{1}})\phi(\vec{r_{2}})(\coshar_{1}+\cosh ar_{2})(1+0.5 r_{12}e^{-b r_{12}}) \end{equation} where$\vec{r_{1}}$ and $\vec{r_{2}}$ are the coordinates of two electrons and$r_{12}=|\vec{r_{1}}-\vec{r_{2}}|$, can be made highly accurate by optimizing$a$, $b$ and $\phi$. This is done by solving a variationally derived equationfor $\phi$ for a given $a$ and $b$ and finding $a$ and $b$ so that theexpectation value of the Hamiltonian is minimum. For the set $\{a, b, \phi\}$the values for various quantities obtained from the above wavefunction arecompared with those given by $204$-parameter wavefunction of Koga et al.[11]and are found to be matching quite accurately(within ppm) with them.

Highly accurate wavefunctions for two-electron systems using two parameteres