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Molecular undercoordination shortens and stiffens the H-O bond but lengthensand softens the O:H nonbond simultaneously associated with O 1s energyentrapment and nonbonding electron dual polarization, which dictates behaviorof water and ice dominated by undercoordinated molecules, such as droplets,bubbles, defects, skins, etc.

Anomalies of water nanobubbles and nanodroplets: molecular undercoordination