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The bandwith, sensitivity and sheer survey speed of the SKA offers uniquepotential for deep spectroscopic surveys of the Milky Way. Within the frequencybands available to the SKA lie many transitions that trace the ionised, radicaland molecular components of the interstellar medium and which willrevolutionise our understanding of many physical processes. In this chapter wedescribe the impact on our understanding of the Milky Way that can be achievedby spectroscopic SKA surveys, including "out of the box" early science withradio recombination lines, Phase 1 surveys of the molecular ISM using anomalousformaldehyde absorption, and full SKA surveys of ammonia inversion lines.

The ionised, radical and molecular Milky Way: spectroscopic surveys with the SKA