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The silicon-vacancy centre (SiV) in diamond has interesting vibronicfeatures. We demonstrate that the zero phonon line position can be used toreliably identify the silicon isotope present in a single centre. This is ofinterest for quantum information applications since only the silicon 29 isotopehas nuclear spin. In addition, we demonstrate that the 64 meV line is due to alocal vibrational mode of the silicon atom. The presence of a local modesuggests a plausible origin of the isotopic shift of the zero phonon line.

Isotopically varying spectral features of silicon vacancy in diamond