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The desorption kinetics was modelled with the both interface- and surfacereactions as rate-controlling steps. It has been shown analytically, that inthe model of 'shrinking core' desorption, the finite hydride-decomposition-ratecauses a modified slope of kinetics. The dependence of desorption time on thepowder particle size has the same power of order as for the surface controlleddesorption.

A Model of Hydrogen Desorption Kinetics Controlled both by Interface and Surface Reactions for Metal Hydrides