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The influence of La and Nd co-substitution on the structural and magneticproperties of BiFeO3 (BFO) thin films was examined. Epitaxial thin films ofpure and, La and Nd co-doped BFO on the SrRuO3 buffered single crystal SrTiO3(001) substrate were deposited using pulsed laser deposition. The structuralchange in co doped La and Nd BFO thin films which was caused by the changes offorce constant in the crystal lattice induced by ionic radii mismatch wasinvestigated. Raman spectroscopy studies manifest the structural change indoped BFO films from rhombohedral to monoclinic distorted phase which isinduced by the co substitution of La and Nd. Room temperature magnetichysteresis curves indicated that saturation magnetization is enhanced in thedoped film with saturation magnetization of ~20 emu/cm3. The dielectric andmagnetic properties are effectively improved in BLNFO films compared to pureBFO thin films.

Modification in structural, dielectric and magnetic properties of La and Nd co-substituted epitaxial BiFeO3 thin films