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The equilibrium size distribution function of clusters (nanoparticles) in thesystem of finite number of molecules (atoms) in finite closed volume withconstant total energy (isolated system) is found using methods of statisticalthermodynamics. The distribution function is found from kinetic equation ofnucleation using one-drop approximation for both isothermal and isolatedsystems. The results obtained are compared with computer simulation data offinite two-dimensional system.

Equilibrium size distribution function of clusters in finite system