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We estimate the radiative quenching rate of the $^{40}$Ca - $^{174}$Yb$^{+}$molecular ion and find that it under-estimates the value reported in recentexperiments by about 5 orders of magnitude. We comment on possible explanationsfor this large discrepancy.

Comment on "Measurement of a large Chemical Reaction Rate between  Ultracold Closed-Shell ^{40}Ca Atoms and Open-Shell ^{174}Yb^{+} Ions Held in  a Hybrid Atom-Ion Trap"