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"Generalized Gibbs' approach" of Schmelzer et al [J. Chem. Phys. 119, 6166(2003); 124, 194503 (2006)] results in wrong conditions of equilibrium of acritical embryo with the ambient phase. The presented analysis shows theshortcomings of this approach and proves the thermodynamic conditions ofequilibrium. Also, a generalized adsorption equation is obtained in differentforms.

Comment on "generalized Gibbs' approach" [J. Chem. Phys. 119, 6166 (2003); 124, 194503 (2006)]