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CaCO3 crystals' physical properties, such as polymorphism and hence thereflectivity and stability, are critical factors of their qualities inindustrial applications. Factors such as additives and substrates thatinfluence CaCO3 polymorphism have been intensively studied. However, theeffects of ionic strength created by varying additives are seldom paidattention to. This study is analyzing how ionic strength of the growth solutioninfluences the crystalline structure of CaCO3, by applying growth solutionscontaining different types of cations of varying concentrations, K+, Na+, andNH4+. This study reveals that the ionic strength plays a significant role inpolymorph selection in the way that the percentage of vaterite among theprecipitates increases with the concentration of ionic strength.

Influence of Ionic strength on calcium carbonate (CaCO3) polymorphism