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Recent surface force apparatus (SFA) and atomic force microscopy (AFM) canmeasure force curves between a probe and a sample surface in solvent. The forcecurve is thought as the solvation structure in some articles, because its shapeis generally oscilltive and pitch of the oscillation is about the same asdiameter of the solvent. However, it is not the solvation structure. It is onlythe force between the probe and the sample surface. Therefore, this brief paperpresents a method for calculating the solvation structure from the force curve.The method is constructed by using integral equation theory, a statisticalmechanics of liquid (Ornstein-Zernike equation coupled by hypernetted-chainclosure). This method is considered to be important for elucidation of thesolvation structure on a sample surface.

A method for calculating solvation structure on a sample surface from a force curve between a probe and the sample: One-dimensional version