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Electron transport through molecular bridge shows novel quantum features.Propogation of electronic wave function through molecular bridge is completelydifferent than individual atomic bridge employed between two contacts. In caseof molecular bridge electronic wave propagators interfere and effect conductionthrough molecular bonding and anti-bonding states.In the present work i showedthrough simple calculation that interference of electronic wave propagatorscause asymmetric propagation of electronic wave through bonding andanti-bonding state. While for hydrogenic molecule these propagators interferecompletely destructively for bonding state and constructively for anti-bondingstate, giving rise to only one peak in spectral function for anti- bondingstate.

Asymmetric propagation of electronic wave function through molecular bonding and anti-bonding states