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The ALICE TPC provides excellent charged particle tracking for the study ofpp and Pb-Pb collisions at LHC. The TPC also allows particle identification viathe measurement of the specific ionisation dE/dx. At high pT (pT > 3 GeV/c)this is accomplished in the region of the relativistic rise of the energy loss.From the energy loss distributions the yields of charged pions, kaons, andprotons can be determined in bins of pT and pT-spectra are constructed. Here wepresent the performance of such an analysis in pp collisions at 7 TeV forcharged pions up to 10 GeV/c.

Charged pion identification at high pT in ALICE using TPC dE/dx