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Recently there has been great interest in Glycol-Water chemistry andsolubility and temperature dependent phase dynamics. The Glycol-Waterbiochemistry of interactions is present in plant biology and chemistry, is ofgreat interest to chemical engineers and biochemists as it is a paradigm ofCarbon-Hydrogen Water organic chemistry. There is an interest moreover informulating a simpler theory and computation model for the Glycol-Waterinteraction and phase dynamics, that is not fully quantum mechanical yet hasthe high accuracy available from a fully quantum mechanical theory of phasetransitions of fluids and Fermi systems. Along these lines of research interestwe have derived a Lennard-Jones -like theory of interacting molecules-Water ina dissolved adducts of Glycol-Water system interacting by Hydrogen bonds whosevalidity is supported at the scale of interactions by other independentmolecular dynamics investigations that utilize force fields dependent on theirexperimental fittings to the Lennard-Jones potential and where we have relaxedor generalized the potential to arbitrary and possibly fractional powers. Thetheory then is a semi-classical theory as the repulsion of particles isincorporated in the Lennard-Jones -like potential's energy required to bringtwo molecules together, a repulsion of sorts. We derive distributions for themolecular species that are exactly solved, and are derived from maximumentropy, here the semi-classical analogue of the Hamiltonian superposition ofquantum phase theory of fluids. We also derive the similar statistics from themicroscopic SDEs stochastic differential dynamics equations, verifying themacroscopic state function entropic-thermodynamic derivation.

Glycol-Water Interactions and co-existing phases and Temperature Dependent Solubility. An Example Of Carbon-Hydrogen Chemistry In Water