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The alloying behaviour of Zn-In liquid alloys at 700K has been studied by using Flory’s model which is a statistical mechanical model. In this model we assume the role of interchange energy (ω) and size factor ф, Φ = θB/θA, where θB > θA, θi (i=A,B) represent the atomic volume of the constituent species of the atomic volume of the alloys. The thermodynamic properties and microscopic properties have been computed. Surface property is studied with the help of Butler’s model while viscosity is computed from Kaptay equation, and the Moelwyn-Hughes equation. Both the viscosity and surface tension of the alloy increase with increase in concentration of Zn, and computed viscosity show small negative deviation. In this work, the value of interchange energy(ω) is found to be positive which suggests that there is a tendency of like atoms pairing (ZnZn and In-In),as the nearest neighbours indicating the phase separation or segregation in Zn-In liquid alloys. The temperature dependence of interchange energy (ω) has been found during the computation of energy of mixing(SM) and heat of mixing (HM).

Thermodynamic, Microscopic and Surface Properties of Zn-In Liquid Alloy at 700 K