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The aromatic aldehydes viz. p-chlorobenzaldehyde, p-hydroxy benzaldehyde, p-nitrobenzaldehyde, p- methoxybenzaldehyde, 4-hydroxy-3-methoxybenzaldehyde and benzaldehyde dissolved in aqueous acetic acid, were oxidized in quantitative to good yields by 50% H2O2 in presence of traces of IrCl3. Conditions for highest yields, under most economical conditions, were obtained. Higher catalyst concentrations decrease the yield. Oxidation in aromatic aldehydes is selective at aldehydic group only, and other groups remain unaffected. In this new, simple and economical method, which is environmentally safe and requires less time, (IrCl5H2O) 2-

Environmental Friendly Conversion of Organic Compounds with H2O2 In The Presence Of Iridium (iii)