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A series of new 1:1 and 1:2 adducts of Bis(morpholinedithiocarbamato)copper(II) with nitrogen and oxygen donors with general formula (Cu(morphdtc)2L) and (Cu(morphdtc)2L2) respectively (where L= 2-ethylpyridine, 2, 4, 6-collidine, dimethylsulphoxide and hexamethyl- phosphoramide) have been synthesized. The addition complexes have been characterized by elemental analysis, conductivity measurements, magnetic susceptibility measurements, TGA/DTA, infrared and electronic spectral studies. These studies suggest that 1:1 adducts are paramagnetic and may be assigned square pyramidal structure while 1:2 adducts are paramagnetic in nature and have a distorted octahedral structure. Antifungal activity of some adducts have been carried out against the fungal strain Sclerotium rolfsii.

Preparation and Characterization of the Adducts of Bis(morpholinedithiocarbamato)copper(II) with Nitrogen and Oxygen Donor Ligands